Catalytic oxidation of THF with homo and hetero metallic Mo/Ru complexes and molecular oxygen q
نویسندگان
چکیده
The novel complex IndðCOÞ3Mo–RuðCOÞ2Cp (1) (Ind 1⁄4 g-indenyl;Cp 1⁄4 g-cyclopentadienyl), as well as other hetero and homo metallic complexes of molybdenum and ruthenium are catalyst precursors in the aerobic oxidation of THF under ambient conditions. Selectivities towards c-butyrolactone of up to 70% are obtained. For the first time in this transformation, propylformate is isolated besides the lactone. 2002 Elsevier Science B.V. All rights reserved.
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